詳細(xì)內(nèi)容：PA12 3035JU3┌PA12 3035JU3 TPE美國道康寧G80A 41 PPO 基礎(chǔ)創(chuàng)新塑料 N1150 PBT馬來西亞巴斯夫B4406G6 PA612美國杜邦FE340025 HDPE中石油獨山子DGDX-6095 PA66南亞6410G5 GBK1 PPO 基礎(chǔ)創(chuàng)新塑料(日本) PX2938POM 日本寶理 AW-01XAP PC韓國LG GN-1006FMR PBT廣州LGGP-2306FY AS(SAN)德國科思創(chuàng)（拜耳）552495 PA12 瑞士EMS TR55LX PBT歐盟杜邦SK601 NC010 PP韓國韓華道達爾SH52C HIPS韓國錦湖HI-425 PA66荷蘭DSM J-17/30/V0 BK POM 日本三菱工程 F20-03 PETG 美國伊士曼 Z6018 ABS奇美PA-707 PVDF 美國蘇威 20810-30 PA612 美國TLC J-4/35/TF/15 HDPE沙特�？松�美孚HTA-001HD TPU拜耳優(yōu)得TPU-TPS LCP日本新石油化學(xué)MG350 HDPE韓國油化P600 AS(SAN)寧波LG80HF-ICE PVC德國K707E PBT基礎(chǔ)創(chuàng)新塑料420SE0 BK1066 PEEK 吉林中研高塑 550CA30 ABS馬來西亞東麗450Y MH5 PP韓國大林HP552R PC/ABS 奇美 PC-345 PVDF 美國蘇威 TA-11008/0001 ABS臺化AF3535 PBT長春4130-104D PA12 3035JU3┌PA12 3035JU3 PA12 3035JU3┌PA12 3035JU3 LLDPE The production of LLDPE begins with the transition metal catalyst, especially the type of Ziegler (Ziegler) or PHILPS Phillips. A new process based on the catalyst for the cyclic olefin metal derivatives is another option for LLDPE production. The actual polymerization can be carried out in the solution and gas phase reactor. Both LDPE and LLDPE have excellent rheological or melt fluidity. LLDPE has smaller shear sensitivity because it has a narrow molecular weight distribution and a short branched chain. During the shear process (for example, extrusion), LLDPE maintains a greater viscosity, and thus is difficult to be processed than the same melting index of LDPE. In extrusion, the lower shear stress of LLDPE makes the stress relaxation of polymer chains faster, and the sensitivity of physical property to the change of blow up ratio is reduced. In the melt extension, LLDPE usually has lower viscosity at various strain rates. That is to say, it will not strain hardening as the LDPE is stretched. The increase in the deformation rate of polyethylene (.LDPE) shows an astonishing increase in viscosity, which is caused by molecular chain entanglement. This phenomenon is not observed in LLDPE, because the lack of long branched chains in LLDPE makes the polymer not entangled. This performance is very important for the application of thin films, because the LLDPE thin films are easy to make thin films under high strength and toughness. Classification /LLDPE PA12 3035JU3┌PA12 3035JU3 PA66深圳杜邦70G43L NC ABS荷蘭盛禧奧（斯泰�。�3904 PP基礎(chǔ)創(chuàng)新塑料(上海)37T1020U-00900 HDPE泰國BPEHD 7000 F PA12 瑞士EMS TRV-4X9 PETG 韓國SK WP-75 MS日本電氣化學(xué)DL-605 PC日本三菱工程 GS-2030MKR PBT日本寶理3165 EF2001 PC/ABS 德國科思創(chuàng)（拜耳） FR3009 PC韓國三星 IH-1043 K2261 ABS韓國三星UT-0510T PMMA 南通三菱麗陽 FFF PPO 基礎(chǔ)創(chuàng)新塑料 GFN1-701S PBT江蘇長春4830 NCB AS(SAN)寧波臺化NF2200AE PA6德國巴斯夫B3EG3 PEI 基礎(chǔ)創(chuàng)新塑料 ATX203R TPU德國巴斯夫690AU PEI 基礎(chǔ)創(chuàng)新塑料 LTX901A PC/ABS 基礎(chǔ)創(chuàng)新塑料 LG9000 PC韓國三星 CF-3200 PA12 法國阿托菲納 3533 PC/ABS 德國科思創(chuàng)（拜耳） 1518B TPU德國巴斯夫LP9273 PFA 美國杜邦 MP-102 PVDF 日本吳羽 KF850 PA6T 日本東洋紡織 TY-761HX12 PC伊朗國家石化 PGPC1215 PC基礎(chǔ)創(chuàng)新塑料 HF1110R-111 PA66美國泰科納GF40-01 PC韓國LG 1603-03 PC基礎(chǔ)創(chuàng)新塑料 ERL0363 TPE荷蘭DSM4380 HIPS韓三星第一毛織VL-1823S PA12 3035JU3┌PA12 3035JU3 PA12 3035JU3┌PA12 3035JU3 LLDPE Atlas According to the type of copolymerized monomers, LLDPE is mainly divided into 3 kinds of copolymers: C4 (butene -1), C6 (hexene -1) and C8 (octene -1). Among them, butylene copolymer is the largest LLDPE resin in the world, while hexene copolymer is the fastest growing LLDPE variety at present. In the LLDPE resin, the typical dosage of the copolymerized monomer is 5% to 10%, with an average amount of about 7%. The metallocene based LLDPE plastic body (mLLDPE) has more than 3 times the average content of the average copolymerized monomer of the traditional LLDPE. Figure 1 shows that the world is 10 years since their 3 monomers yield of LLDPE. At the end of 1984, the co carbon company introduced the production of hexene copolymerized LLDPE, followed by Exxon, Mobil and other companies. Dow Chemical (Dow Chemical Company) almost used octylene as comonomer in its low pressure solution process, and NOVA Canada (Nova chemical) also used octylene in most of the pressure solution process. The copolymerization of octyl LLDPE resin has a little good strength, tearing resistance and processing property, but the properties of hexene copolymerization and octyl copolymers have little difference. Hexene LLDPE resin manufacturers including ExxonMobil Chemical (Exxon Mobil chemical company), Eastman Chemical (Eastman Chem Co), Equistar (star company) and Chevron Phillips (Chevron Phillips chemical company) etc.. In addition, Dow Chemical (Dow Chemical Company), Basell (Basel), Innovene (Samsung, Total, innoven) (Samsung Total (micro-blog), etc.) also produce 1-hexene LLDPE. Compared with the commonly used butene copolymers, the LLDPE produced by hexene and octene as copolymerized monomers has better performance. The largest use of LLDPE resin in film production, with a long chain alpha olefin (such as cyclohexene, 1-octene) as comonomer production of LLDPE resin and film products in the tensile strength, impact strength, tearing strength, penetration resistance, environmental stress cracking resistance and many other aspects are better than by butene as comonomer to produce LLDPE resin. Since 1990s, PE manufacturers and users in foreign countries tend to replace butylene with hexene and octene. It is reported that using octene as comonomer, the performance of resin is not necessarily better than that of hexene copolymerization, and the price is more expensive. Therefore, the trend of using LLDPE abroad to replace butene is more obvious. PA12 3035JU3┌PA12 3035JU3 LCP日本寶理A470 PEI 基礎(chǔ)創(chuàng)新塑料 LTX930A TPU美國RON R390U TPE美國 APEXTB-6000-45 PC日本三菱工程 GS2030P BK PA66德國巴斯夫A3XG5 PVC內(nèi)蒙古烏�；�工SG-5 PA612瑞士EMS CR-9 PC日本帝人 G-3410 NC PBT新光4800 PC日本三菱工程 GSN-2030R2 SBS日本科騰D1101 JO PP韓國大林1073 POM 德國巴斯夫 W5320-003 PP韓國韓華道達爾RJ7605 PA6無錫朗盛BKV15H1.0 PFA 美國杜邦 MP-501 LDPE沙特�？松�美孚LD 150AC HDPE中石化茂名4003 ABS奇美PA-763 TPU拜耳優(yōu)得UK-85A10 PC基礎(chǔ)創(chuàng)新塑料 DFL4034 TPV 美國�？松�美孚 8201-70 PP中石化茂名F300M PC/ABS 廣州LG GN-5007FL PVC德國EP7555 PA66漳州長春21G5-104 PP基礎(chǔ)創(chuàng)新塑料G3240A PP惠州南亞3219M5 PA66基礎(chǔ)創(chuàng)新塑料(南沙)RFL4536 PA46荷蘭DSM TW250F6 ABS日本東麗982 PC日本三菱工程 EFR3000 BK PEEK 英國威格斯 450G PA12 3035JU3┌PA12 3035JU3 PA12 3035JU3┌PA12 3035JU3 Because there is no large-scale production of hexene and octene in China, and the import price is more expensive, the LLDPE resin currently used in China is mainly used as butene as comonomer. Some enterprises in China used the LLDPE as the monomer of the comonomer when they introduced the production plant, but they had to give up because of the production of no hexene in China, and only imported a small amount of hexene when driving. Most of the high grade LLDPE imported from China are such products. It is expected that in the future, there will be a greater increase in the demand for LLDPE with 1- hexene as a monomer. Performance /LLDPE Cold tolerance of LLDPE, the relationship between catalytic temperature and melt flow rate of LLDPE brittle temperature than LDPE, HDPE are low, which indicates that the resistance to low temperature. Physical and mechanical properties PA12 3035JU3┌PA12 3035JU3 POM 美國杜邦 460 PC日本高達 K-40 LDPE中石化茂名818A LCP日本上野6040GM LLDPE中石化廣州DNDA-5001 PP福聚PT100 LLDPE韓國SKRG500U PA46荷蘭DSM TW248F6 BK PA66星一NGF1220A PA66美國首諾20NSP NC TPU深圳科思創(chuàng)（拜耳）UT1-95A10 PP寧波臺塑5090T FEP 美國杜邦 5100-JPC日本三菱工程 GS2010IR PBT江蘇營口康輝KH2083 PC日本帝人 G-3430RF POM 韓國工程塑料 FL2020 PP惠州南亞3117 ENC2 ABS韓國錦湖710 TPV 荷蘭DSM 4139DBLLDPE臺塑3224 PA6荷蘭DSM K-FHG12 PP中石油撫順Z30S PETG 美國伊士曼 Z6011 PC日本帝人 G-3415H BK PA6湖南岳化YH3400 PP寧波臺塑1250 PA6法國羅地亞C216V40 TPU深圳科思創(chuàng)（拜耳）U-98AU10 PMMA 日本三菱麗陽 IRD-70 PC/ABS 韓國三星 GC-1150 PA6德國朗盛BKV30H1.0 LCP日本油墨LD-240 BK TPE美國吉力士CL2042X PA6瑞士EMS BZ 1 PA12 3035JU3┌PA12 3035JU3 PA12 3035JU3┌PA12 3035JU3 MDPE molecular structure In the main chain of MDPE molecule, there are 20 methyl branched chains or 13 ethyl branched chains on the average of every 1000 carbon atoms, and their performance depends on the number and length of branched chain. Copolymerization can increase the link chain between small crystals of its crystal Performance characteristics and parameters MDPE is characterized by long term retention of resistance to environmental stress and strength. The relative density of MDPE is 0.926-0.953, the crystallinity of 70%-80%, the average molecular weight is 200 thousand, the tensile strength is 8-24 MPa, elongation at break of 50%-60%, the melting temperature of 126-135 DEG C, the melt flow rate of 0.1-35 g /10 minutes, the heat deformation temperature of 49-74 DEG C (0.46 MPa). Processing technology PA12 3035JU3┌PA12 3035JU3 PBT長春4115 BK LCP美國杜邦6130 WT010 PC基礎(chǔ)創(chuàng)新塑料 SLX1231T PBT韓國可隆KP212G15VO PP日本卡爾普FR-913 PMMA 日本三菱麗陽 VKL40F PA6基礎(chǔ)創(chuàng)新塑料PX09322 WH LDPE臺聚NA112-27 PA6瑞士EMS BT40Z ABS韓國錦湖750 PC日本出光 LC1700 PA66基礎(chǔ)創(chuàng)新塑料RF-7007HS BK PC臺化 AC3830-AD PPS菲利普R-4-200BL PP星一PF-02 TPEE荷蘭DSM EM740 TPE荷蘭DSMEL740 POM 日本三菱工程 F20-54 PMMA 法國阿科瑪 V825T-101 PA66南亞6512PC日本三菱工程 EHR3100T POM 美國杜邦 500AL PA66上海羅地亞AR218V30 BK MVLDPE(茂金屬)新加坡埃克森美孚1018HA PBT日本東麗1401X07PEI 基礎(chǔ)創(chuàng)新塑料 1010M PC基礎(chǔ)創(chuàng)新塑料(南沙) BPL1000 BK IXEF 德國蘇威 1022-9008 PA6T 日本三井化學(xué) E430NH T5 PPS日本油墨FZ-3600-L3 SBS中石化巴陵YH-188 PP日本卡爾普FR-913 TPU拜耳優(yōu)得UD-85AU10 HDPE美國陶氏17450N PC/ABS 基礎(chǔ)創(chuàng)新塑料 CX7211 PA12 3035JU3┌PA12 3035JU3 PA12 3035JU3┌PA12 3035JU3 It is divided into three kinds: high pressure method, low pressure method and medium pressure method. High pressure method is used to produce LDPE. This method has been developed very early. Polyethylene produced by this method accounts for about 2/3 of the total output of polyethylene. However, with the development of production technology and catalyst, its growth rate has lagged behind the low pressure method. The low pressure method includes slurry method, solution method and gas phase method for its application. Slurry method is mainly used to produce HDPE, while solution method and gas phase method can not only produce HDPE