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詳細(xì)內(nèi)容:PA12 SF004S↘PA12 SF004S HDPE沙特TASNEEB1258 LDPE中石化茂名1810D HDPE加拿大諾瓦化學(xué)IG464-C TPE德國膠寶TC5PGZ EPDM 美國LION 694 PA66瑞士EMS A70 GF30H COC美國大賽璐8007S-04 PBT漳州長春3015-104S PETG 美國伊士曼 EB062 PA66日本杜邦77G33HS1L NC010 PA6日本三菱工程1013GH30 BK701 POM 韓國工程塑料 F20-03 LOF POM 韓國工程塑料 F30-01 PC基礎(chǔ)創(chuàng)新塑料 DX14354X LLDPE沙特埃克森美孚LL 1002KW PA66美國杜邦70G13HS1-L EVA臺聚UE649-04 POM 日本三菱工程 F20-03 PP中石化茂名PPB-M02D PBT長春4830G TPU德國巴斯夫1195A10 LCP美國杜邦6140L BK010 TPV 美國?松梨 151-50 PA66日本東麗CM3001-N/BK PC三菱化工 M7027BF PETG 美國伊士曼 DN001HF PA66日本旭化成1402S B3306 TPU美國路博潤GP95AE TPU德國巴斯夫ES90A11 PETG 美國伊士曼 CN015 PA6日本三菱工程1015G20 TPE日本JSR1320P PVC廣州東曹TG-1000S LLDPE中石化茂名3012 PA66瑞士EMS BT40Z PA12 SF004S↘PA12 SF004S PA12 SF004S↘PA12 SF004S HIPS Impact resistant polystyrene (HIPS) is an impact resistant polystyrene product produced by adding polybutadiene rubber particles in polystyrene. introduce 475 is the HIPS machining PA12 SF004S↘PA12 SF004S LCP日本寶理C130 PP臺化T1002 POE韓國SK891 PA6日本宇部1013IU50 BK PBT韓國LGGP-1006FD TPU德國科思創(chuàng)(拜耳)9392AU POM 日本寶理 KT-5M PP福聚6331 PBT新光B0620FC BK LCP日本寶理T130 PC日本高達(dá) R-10 PC基礎(chǔ)創(chuàng)新塑料 HF1130-112 TPUS-198A PMMA 英國璐彩特 CP-51A PPS深圳東麗A130MX04 EVA美國杜邦636 PVC南通吉匯化工7356 PP中石油大連H39S PA66日本東麗CM3007 TPE美國杜邦5526 PA66美國杜邦WRF403 NC010 PBT美國泰科納6500 BK LCP美國泰科納E488ID-2 LCP日本寶理E130 VF2001 PA66日本杜邦ST801 PC/ABS 德國科思創(chuàng)(拜耳) FR86- ABS韓國巴斯夫EGP-7 GPPS臺化GP5500EMA美國杜邦2116AC PC泰國三菱工程 M7027BF GPPS中石化廣州525 PBT日本三菱工程5710G30-S2-BK TPE日本JSRRB810 SURLYN美國杜邦PC2000 PA66德國巴斯夫C40 NC PA12 SF004S↘PA12 SF004S PA12 SF004S↘PA12 SF004S The impact resistance of PS can be processed by many traditional molding methods, such as injection molding, structural foam molding, sheet and film extrusion, hot forming and blow molding. HIPS resin absorbs water slowly, so there is no need for drying in general. Sometimes excessive moisture on the surface of the material will be absorbed, which affects the appearance quality of the final product. Under the temperature of 160 F dry 23h can remove excess moisture. The extrusion of thin films, sheets and profiles is the most useful processing method for HIPS. Anti impact polystyrene has a wide range of processing, so it becomes one of the most easily thermoforming resins. Generally, the melting temperature of the resin is 400 - 500 F, and the melt index range of the resin is 1.5 - 4 g/10min. Rotating, series and shuttle type pressure and vacuum thermoforming equipment are often used. HIPS has excellent thermal stability and shear stability. It can be used for a lot of recycled materials without reducing the performance of products, and the amount of recycled material in hot forming can be as high as 60%. PA12 SF004S↘PA12 SF004SPC/ABS 沙伯基礎(chǔ) C7230P TPUAH-670 PC韓國LG 1301-10 PA66美國杜邦72G33HS1L PC泰國三菱工程 S-2000UR PC韓國三星 SC-1102UR TPV 美國埃克森美孚 60ANS200 PA612 美國杜邦 77G33HSIL PA6荷蘭DSM K224-HPG3 HDPE沙特SABICM80064F PFA 法國蘇威 MFA 1540 PBT新光356BN7 PC基礎(chǔ)創(chuàng)新塑料(南沙) XHT4141 NA5D001T PA612 日本宇部 7115U HIPS美國陶氏1400 GPPS湛江新中美525(藍(lán)底) POM 日本旭化成 Z3510 PP臺化K2051 PVC德國P4472PFA 日本旭硝子 P-61XP TPEE美國杜邦4056 PA46荷蘭DSM TE250F6 BK ABS奇美PA-764 PBT新光4883 PA6印度朗盛BKV30 000000 PC德國科思創(chuàng)(拜耳) 2407 PVDF 法國阿科瑪 2800-00 PP北歐化工BD950MO LCP日本東麗LX70G35 F PPS日本出光C-220SC LLDPE中石化天津TJZS-2650 PA66深圳杜邦80G25HS PP臺塑1005N PC/ABS 韓國三星 EN-1052 PVC德國P70F PA12 SF004S↘PA12 SF004S PA12 SF004S↘PA12 SF004S Injection molding is the most used processing method next to the extrusion. The injection molding of the resin is usually carried out on a reciprocating screw injection molding machine with a length to diameter ratio of 16:1 to 24:1 and a compression ratio of 2.5/1 - 3.0/1. The processing temperature is 350 - 500 degree F, but for the flame retardant HIPS, the processing temperature must be less than 470 F to prevent the additive from producing degradation reaction. The melt index of the resin processed by injection molding is generally 5 to 15 g/min. The forming method of structural foam plastics is a common process, using chemical and physical foaming agents. Although a variety of HIPS resin are compatible with each other, but before the operation to clean processing equipment, to ensure good product quality, the impact of acrylonitrile with a PS Th ene styrene copolymer (ABS), polyvinyl chloride (PVC), polypropylene (PP), polyethylene (PE), acrylic resin and most other plastics are not compatible, incompatible plastic mixture separation will produce delamination phenomenon in processing equipment, caused great decline of physical properties. application PA12 SF004S↘PA12 SF004S POE韓國SK871L PBT江蘇長春1100-211M PETG 韓國SK KN200 PA66韓國可隆KN333G15BL HIPS馬來西亞出光HT50 TPU德國科思創(chuàng)(拜耳)U-95A PPO 基礎(chǔ)創(chuàng)新塑料 PX1007 PPE 日本旭化成 EV08PA1010 美國杜邦 RS LC1600 PP北歐化工RB307MO PE蠟 泰國SCG化工 LP0600FPC/PET 基礎(chǔ)創(chuàng)新塑料 XL1339 PC韓國三星 CF-3300HF AS(SAN)鎮(zhèn)江奇美PN-138H PC基礎(chǔ)創(chuàng)新塑料(南沙) 123SRM PPS日本油墨TCS3515 POM 基礎(chǔ)創(chuàng)新塑料 KFL-4416 PC日本出光 URZ2500 PBT美國泰科納UCF2020 LCP美國杜邦3226 BK PBT基礎(chǔ)創(chuàng)新塑料(上海)DR48-1001 PEEK 美國殼牌 DBF1G31-BK PP中石油大慶PA14D-1 PA66瑞士EMS GV-4H PC日本三菱工程 ECF2008 PPO 基礎(chǔ)創(chuàng)新塑料 PCN2910 PA66南亞6410G3 ABK2 LDPE伊朗國家石化LT750 EVA中石化燕山14J4 TPU德國科思創(chuàng)(拜耳)255(粉) PC日本出光 LC1500MPC/ABS 日本 F-735 S101 PC/ABS 日本住友化學(xué) H260 PC韓國三養(yǎng) 3025IR POM 日本杜邦 DE-9422 PA12 SF004S↘PA12 SF004S PA12 SF004S↘PA12 SF004S Impact resistance PS is easily machinability, good performance and low price, so it is used to manufacture products and industrial products of many uses. The main applications are packaging and disposable supplies, instruments, household appliances, toys and entertainment supplies, and construction industries. The largest use of HIPS is to be used as a packaging and disposable material, especially for food packaging and eating tableware. The main applications include the daily packaging container. A cup, a variety of covers, plates, bowls, etc. are used and distributed for the vending machine. Disposable products such as disc, bottle cap, safety razor, pen and so on are also a part of the use of HIPS. PVC carcinogen, which will undoubtedly affect the development of PVC to some extent. However, the residual VCM has been successfully reduced by vehicle and other ways, so that the content of VCM in PVC resin will be less than 10ppm, which will meet the requirement of hygienic grade resin and expand the application scope of PVC. Even the content of VCM in the resin is less than 5ppm, and the residual VCM is very few after processing. It is basically harmless to the human body and can be used as food and medicine packaging and children's toys. Main classification PA12 SF004S↘PA12 SF004S PC奇美 PC -6600 PP中石化茂名V30GPC基礎(chǔ)創(chuàng)新塑料 EXL1414T PVC韓國韓華KH-31S TPV 美國?松梨 591-73 PP日本大賽璐PG4N1 PA12 法國阿科瑪 P20 PP新加坡聚烯烴FS5611L PC日本帝人 LN-2350SG PBT基礎(chǔ)創(chuàng)新塑料364 POM 日本旭化成 5010 PA66深圳杜邦HTNFR52G30NH NC010 PA6荷蘭DSM K224-TG9 PC泰國三菱工程 GN-2030R2 PC/PET 上海高能 E1803 PPO 日本旭化成 X304H TPE美國吉力士G7950-1 ABS寧波LGHI-130 HDPE沙特埃克森美孚HTA-108PC基礎(chǔ)創(chuàng)新塑料(南沙) HF1130-111 PBT日本三菱工程5308GN2-15 EPDM 日本三井化學(xué) 3072EPM TPEE美國杜邦4069 PP荷蘭利安德巴塞爾HP162PPS日本寶理1140A62 HD9101 POP美國陶氏EG8200G PA66日本杜邦HTN51G35EF K(Q)膠日本旭化成845 TPE美國吉力士CL2000X PP茂名實(shí)華045(粉) PC韓國三星 NH-1023H BK PBT日本寶理7195W POM 德國赫斯特 C13021 BK ABS韓國LGAF312B ABS日本百富化工BF-777B PA12 SF004S↘PA12 SF004S PA12 SF004S↘PA12 SF004S According to the different application range, PVC can be divided into general PVC resin, high degree of polymerization PVC resin and crosslinked PVC resin. The general PVC resin by polymerization of vinyl chloride monomer is formed under the action of initiator; high degree of polymerization of PVC resin is resin in the polymerization of vinyl chloride monomer added to the system, the chain growth polymerization crosslinking agent; PVC resin is added to the resin crosslinking agent containing dienes and polyenes in vinyl chloride monomer polymerization polymerization system. According to the method to distinguish the vinyl chloride monomer, can be divided into electric stone, and imported ethylene (EDC, VCM) monomer method (on the habits of the ethylene monomer and import system called ethylene method). According to polymerization method, PVC can be divided into four main categories: suspension polyvinyl chloride, emulsion polymerization, polyvinyl chloride, bulk polymerization, polyvinyl chloride and solution polyvinyl chloride. Suspension polyvinyl chloride (PVC) is one of the most productive varieties, accounting for about 80% of the total output of PVC. Polyvinyl chloride suspension method is divided into six models according to absolute viscosity: XS-1, XS-2... XS-6; XJ-1, XJ-2... XJ-6. The meaning of each letter in the model: X- suspension; S- loose type; J- compact. method PA12 SF004S↘PA12 SF004S PC日本三菱工程 RS-2001R PC基礎(chǔ)創(chuàng)新塑料 DFL-34 ABS深圳東麗100 BK ABS日本旭化成IM15 HDPE中石油吉化JHMGC 100S PP美國?松梨赑P7555KNE2 PC/ABS 韓國LG 5001 PBT德國巴斯夫B 4300 G4 PA6德國巴斯夫TG7S PP馬來大騰石化SM-850 PPO 基礎(chǔ)創(chuàng)新塑料 PX9406X PPS菲利普R-7-120BL PC基礎(chǔ)創(chuàng)新塑料(南沙) HF1130R-71257 ABS基礎(chǔ)創(chuàng)新塑料AL-4022 PC基礎(chǔ)創(chuàng)新塑料 HF1140 PA66基礎(chǔ)創(chuàng)新塑料RL-4040 BK8-115- PA46日本DSM N2030B PP中石化上海M800E PVC寧波臺塑S-80 PBT基礎(chǔ)創(chuàng)新塑料508-BK1066 PBT美國杜邦T843FR NC010 PA9T 日本可樂麗 BT1500H PP新加坡聚烯烴FY4012 PC上?扑紕(chuàng)(拜耳) 9425 BK LCP美國泰科納A150D-2 PP沙特?松梨7032E3 PMMA 日本住友化學(xué) MM PPS美國泰科納1140L4 SF3001 AS(SAN)LG惠州SA30PC/ABS 沙伯基礎(chǔ) CY4000 PPS菲利普R-4-230NA EVA巴西BraskemFEV 1260 PPE 日本旭化成 A0210 PVC德國E75SK PA12 SF004S↘PA12 SF004S PA12 SF004S↘PA12 SF004S polyvinyl chloride PVC can be made by substitution reaction of ethylene, chlorine and catalyst. Because of its fire prevention heat effect of PVC is widely used in all walks of life every kind of products: wire skin, skin fiber, shoes, handbags, bags, accessories, signs and billboards, building decoration supplies, furniture, ornaments, rollers, pipes, toys (such as the famous Italy "Rody" jumping horse), curtain, door, auxiliary medical supplies, gloves, some food preservation paper, some fashion etc.. Polymerization method PVC was prepared by free radical addition polymerization. The polymerization methods were mainly divided into suspension polymerization, emulsion polymerization and bulk polymerization, mainly by suspension polymerization, which accounted for about 80% of the total output of PVC. The pure water, liquefied VCM monomer and dispersant were added to the reactor, then initiator and other auxiliaries were added. After heating to a certain temperature, the VCM monomer was polymerized by free radical to form PVC particles. Continuous stirring makes the particle size uniform and makes the generated particles suspended in the water. In addition, the PVC paste resin was produced by micro suspension, and the properties and paste properties of the products were all good. PA12 SF004S↘PA12 SF004S POM 寶理 TF-10LV PC/ABS 德國科思創(chuàng)(拜耳) 3021 WH PP福聚SI0104 EVA泰國石化SV1040 EVA美國杜邦670 TPV 美國?松梨 251-85W232 LLDPE韓國現(xiàn)代UJ814 PA12 美國杜邦 PA2072 PEI 基礎(chǔ)創(chuàng)新塑料 EF1008 PP中石化上海F800E PA66瑞士EMS GM-4H PC基礎(chǔ)創(chuàng)新塑料(南沙) FXD9810 PP中石化廣州F500 PC/ABS 沙伯基礎(chǔ) 8002 MVLDPE(茂金屬)美國陶氏)2036P TPV 荷蘭DSM 3190B PP中石化鎮(zhèn)海T30S POM 日本三菱工程 F20-61 PP南亞PP-3310 ABS韓國三星MP-0670 PA46日本DSM HF5030 BK PC日本帝人 G-3110M PP新加坡聚烯烴FC9413G PC/ABS 日本 T-105 PA66意大利LATI66-20T G/20 PA66韓國羅地亞A 218 W V30 PPO 日本三菱工程 LN23 PBT日本寶理3300-EF2001 PC德國科思創(chuàng)(拜耳) 2407 971000 PC基礎(chǔ)創(chuàng)新塑料(南沙) LUX9612 EVA臺聚UE630 POM 美國杜邦 900P PA6日本尤尼吉可A1022GFL PA66基礎(chǔ)創(chuàng)新塑料RFL-4036 BK PC日本帝人 G-3510G PA12 SF004S↘PA12 SF004S PA12 SF004S↘PA12 SF004S The monomer droplets are dispersed in the aqueous phase suspension polymerization method, using oil soluble initiator were dissolved in monomer, polymerization reaction in the droplet, the polymerization heat absorbed by the water in time, in order to ensure that these droplets in water were bead dispersed, need to join the suspension the stabilizer, such as gelatin and polyvinyl alcohol, methyl cellulose, hydroxyethyl cellulose, etc.. Most of the initiators are organic peroxide and azo compounds, such as peroxide two, two isopropyl carbonate, peroxide two, bicarbonate, peroxide two, two ethylhexyl ester, azo two isoheptane, azo two isobutadiene and so on. The polymerization is carried out in a polymerizer with a agitator. After polymerization, the monomer material flows into the recovery tank or stripper recycle monomer. Then into the mixing kettle, water washing then centrifuge dehydration, drying and resin finished products. The vinyl chloride monomer should be removed from the resin as much as possible. As the PVC for food packaging, the content of free monomer should be controlled below 1ppm. During polymerization, the temperature and pressure of the polymerization process must be controlled to ensure that the specified molecular weight and molecular weight distribution range are obtained and the detonation is prevented. The particle size and particle size distribution of the resin is controlled by the stirring speed and the selection and dosage of the suspension stabilizer. The quality of resin is characterized by particle size and particle size distribution, molecular weight and molecular weight distribution, apparent density, porosity, fisheye, thermostability, color, impurity content and free mobility of powder. Polymerization reaction
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