詳細(xì)內(nèi)容：PA66 12TA】PA66 12TA PBT基礎(chǔ)創(chuàng)新塑料815 PA66法國羅地亞A 30 V25PA12 瑞士EMS TR90LS PA46荷蘭DSM TW200F8 TPV 美國�？松�美孚 123-50W175 PBT美國杜邦SK608 BK509 PC/PET 德國科思創(chuàng)（拜耳） 7665 PP中石油獨山子S2040 PC基礎(chǔ)創(chuàng)新塑料 121 BK2065S TPU德國科思創(chuàng)（拜耳）5377（粉） PPS美國泰科納6165D BK PA66德國弗瑞圣塔A63RV0 PBT馬來西亞巴斯夫B4300G3 PA66惠州南亞6512 電木粉 長春 T373 PP北歐化工BE860MO PBT日本寶理3216 PA6德國朗盛B30S PA66德國AKROA3GF301 PBT日本寶理6304 PA66日本東麗HF3074G30 POM 日本旭化成 LS701 PBT長春3030-104E POE新加坡三井化學(xué)DF840 PBT日本寶理3105 ED3002 HDPE巴西QUATTORHS-5010 LLDPE沙特�？松�美孚3518CB PA6上海古比雪夫氮TNC102 PVDF 美國蘇威 20810-0.1 PA46瑞士EMS TS35O(BK)PA/ABS上海大賽璐A1300 TPEE日本東麗4777 HDPE韓國SK3301 PP美國英力士L12Z-01 EMMA日本住友化學(xué)SWA210 PA66 12TA】PA66 12TA PA66 12TA】PA66 12TA LLDPE The production of LLDPE begins with the transition metal catalyst, especially the type of Ziegler (Ziegler) or PHILPS Phillips. A new process based on the catalyst for the cyclic olefin metal derivatives is another option for LLDPE production. The actual polymerization can be carried out in the solution and gas phase reactor. Both LDPE and LLDPE have excellent rheological or melt fluidity. LLDPE has smaller shear sensitivity because it has a narrow molecular weight distribution and a short branched chain. During the shear process (for example, extrusion), LLDPE maintains a greater viscosity, and thus is difficult to be processed than the same melting index of LDPE. In extrusion, the lower shear stress of LLDPE makes the stress relaxation of polymer chains faster, and the sensitivity of physical property to the change of blow up ratio is reduced. In the melt extension, LLDPE usually has lower viscosity at various strain rates. That is to say, it will not strain hardening as the LDPE is stretched. The increase in the deformation rate of polyethylene (.LDPE) shows an astonishing increase in viscosity, which is caused by molecular chain entanglement. This phenomenon is not observed in LLDPE, because the lack of long branched chains in LLDPE makes the polymer not entangled. This performance is very important for the application of thin films, because the LLDPE thin films are easy to make thin films under high strength and toughness. Classification /LLDPE PA66 12TA】PA66 12TA POM 美國杜邦 DE-20199 LDPE亞聚F1100 ABS韓國三星BF-0370 BK LCP美國杜邦5145 TPEE荷蘭DSM 38D PA66美國首諾R525H BK ABS日本TECHNOH593 PC比利時科思創(chuàng)（拜耳） 3208 PP韓國曉星HJ801R PC日本帝人 LD-1000RM PC/ABS 上�？扑紕�(chuàng)（拜耳） FR3009 ABS日本TECHNOH570 PC日本三菱工程 S-2000R PPS日本出光C-140SF BK PP福聚RP348 PC/ABS 嘉興帝人 TN-7200B PP德國巴塞爾ERG321N POM 德國赫斯特 EC270TX PBT江蘇長春4830 NCF PC嘉興帝人 LN-2520HB BK PBT漳州長春3030-222M PA66基礎(chǔ)創(chuàng)新塑料RF-700-10 PC日本出光 A1900S PA66美國杜邦HTN53G50HSLR PA66基礎(chǔ)創(chuàng)新塑料RFL-4036HS TPU拜耳優(yōu)得US-80AU10 PMMA 英國璐彩特 CP-81A PETG 美國伊士曼 GN046 TPE和泰HA40 PA66德國杜邦FG101L ABS德國科思創(chuàng)（拜耳）150G22 BK PC日本出光 G2510 PA12 德國贏創(chuàng)德固賽 LX9001 TPU德國科思創(chuàng)（拜耳）UH-71DU20 EVA臺聚UE508 PA66 12TA】PA66 12TA PA66 12TA】PA66 12TA LLDPE Atlas According to the type of copolymerized monomers, LLDPE is mainly divided into 3 kinds of copolymers: C4 (butene -1), C6 (hexene -1) and C8 (octene -1). Among them, butylene copolymer is the largest LLDPE resin in the world, while hexene copolymer is the fastest growing LLDPE variety at present. In the LLDPE resin, the typical dosage of the copolymerized monomer is 5% to 10%, with an average amount of about 7%. The metallocene based LLDPE plastic body (mLLDPE) has more than 3 times the average content of the average copolymerized monomer of the traditional LLDPE. Figure 1 shows that the world is 10 years since their 3 monomers yield of LLDPE. At the end of 1984, the co carbon company introduced the production of hexene copolymerized LLDPE, followed by Exxon, Mobil and other companies. Dow Chemical (Dow Chemical Company) almost used octylene as comonomer in its low pressure solution process, and NOVA Canada (Nova chemical) also used octylene in most of the pressure solution process. The copolymerization of octyl LLDPE resin has a little good strength, tearing resistance and processing property, but the properties of hexene copolymerization and octyl copolymers have little difference. Hexene LLDPE resin manufacturers including ExxonMobil Chemical (Exxon Mobil chemical company), Eastman Chemical (Eastman Chem Co), Equistar (star company) and Chevron Phillips (Chevron Phillips chemical company) etc.. In addition, Dow Chemical (Dow Chemical Company), Basell (Basel), Innovene (Samsung, Total, innoven) (Samsung Total (micro-blog), etc.) also produce 1-hexene LLDPE. Compared with the commonly used butene copolymers, the LLDPE produced by hexene and octene as copolymerized monomers has better performance. The largest use of LLDPE resin in film production, with a long chain alpha olefin (such as cyclohexene, 1-octene) as comonomer production of LLDPE resin and film products in the tensile strength, impact strength, tearing strength, penetration resistance, environmental stress cracking resistance and many other aspects are better than by butene as comonomer to produce LLDPE resin. Since 1990s, PE manufacturers and users in foreign countries tend to replace butylene with hexene and octene. It is reported that using octene as comonomer, the performance of resin is not necessarily better than that of hexene copolymerization, and the price is more expensive. Therefore, the trend of using LLDPE abroad to replace butene is more obvious. PA66 12TA】PA66 12TA PA9T 日本可樂麗 G1301A-M61 TPU德國科思創(chuàng)（拜耳）8798 PA6日本東麗CM1030 PA6德國巴斯夫B3ZG8 PPS日本寶理1130T71 PBT日本寶理CN7030LN NC PC/ABS 上海科思創(chuàng)（拜耳） FR3000 POM 日本旭化成 SH510 PVC德國C14/50V POM 韓國工程塑料 FG2020 SEBS美國科騰A1536 MBS韓國LGMB872 PP韓國SK RX5200 ABS基礎(chǔ)創(chuàng)新塑料T-1008 PBT美國杜邦SK665FR PPS韓國三星XP-4240 ABS韓國LGAF303G PA612美國杜邦153HSL- POM 日本三菱工程 FG2025-BK PA6/66德國巴斯夫C40 TPV 美國�？松�美孚 111-64 MS日本電氣化學(xué)TX-400S LLDPE沙特�？松�美孚EFDC-7050 PA9T 日本可樂麗 G1300A PC日本帝人 3730SI PA6T 日本三井化學(xué) C215NK PC泰國三菱工程 GSH2030DT AS(SAN)臺化NF2200AE PBT基礎(chǔ)創(chuàng)新塑料420SEO-1066 PA6基礎(chǔ)創(chuàng)新塑料PFL4038 HS PC/ABS 廣州LG GN5151RFG PPO 基礎(chǔ)創(chuàng)新塑料(南沙) PVX1201 PBT漳州長春3020-200P PP臺化T3002 PP韓國LG M560 PA66 12TA】PA66 12TA PA66 12TA】PA66 12TA Because there is no large-scale production of hexene and octene in China, and the import price is more expensive, the LLDPE resin currently used in China is mainly used as butene as comonomer. Some enterprises in China used the LLDPE as the monomer of the comonomer when they introduced the production plant, but they had to give up because of the production of no hexene in China, and only imported a small amount of hexene when driving. Most of the high grade LLDPE imported from China are such products. It is expected that in the future, there will be a greater increase in the demand for LLDPE with 1- hexene as a monomer. Performance /LLDPE Cold tolerance of LLDPE, the relationship between catalytic temperature and melt flow rate of LLDPE brittle temperature than LDPE, HDPE are low, which indicates that the resistance to low temperature. Physical and mechanical properties PA66 12TA】PA66 12TA TPU美國路博潤A1120 PBT日本三菱工程5010N5 PA66日本東麗CM3001G-15 PA66日本旭化成FR200 PPS日本東麗A470M PA6日本東洋紡織T-422T TPU德國科思創(chuàng)（拜耳）355 POM 美國杜邦 500LM PC德國科思創(chuàng)（拜耳） TP-0284 LCP日本寶理S475 PC日本出光 RE1900 PBT長春5615-104C PEI 基礎(chǔ)創(chuàng)新塑料 PDX-E-99545 PP日本三井化學(xué)MA3 ABS韓國LGGP-2106F PPS日本油墨FZ-1140-D5 BK GPPS新加坡電氣化學(xué)MD-100-301 ABS德國巴斯夫HI-10 TPV 美國埃克森美孚 9111-75 TPEE日本東麗7247W PA6日本東麗CM1017XL2 PA6惠州南亞2210G3 PBT基礎(chǔ)創(chuàng)新塑料EXVX1152-1001 PC/ABS 廣州LG GP-5006BH PFA 美國杜邦 420HP ABS日本東麗500 GPPS上海賽科251P PC/PET 日本帝人 AM9830F PP韓國SK BX3910 PA66美國泰科納GF40-01 PA612 美國杜邦 158 PBT漳州長春3045-104E PA66美國首諾R513H TPU美國亨斯邁98AE PC基礎(chǔ)創(chuàng)新塑料 EXL1414B PA66 12TA】PA66 12TA PA66 12TA】PA66 12TA MDPE molecular structure In the main chain of MDPE molecule, there are 20 methyl branched chains or 13 ethyl branched chains on the average of every 1000 carbon atoms, and their performance depends on the number and length of branched chain. Copolymerization can increase the link chain between small crystals of its crystal Performance characteristics and parameters MDPE is characterized by long term retention of resistance to environmental stress and strength. The relative density of MDPE is 0.926-0.953, the crystallinity of 70%-80%, the average molecular weight is 200 thousand, the tensile strength is 8-24 MPa, elongation at break of 50%-60%, the melting temperature of 126-135 DEG C, the melt flow rate of 0.1-35 g /10 minutes, the heat deformation temperature of 49-74 DEG C (0.46 MPa). Processing technology PA66 12TA】PA66 12TA PA11 法國阿托菲納 M-BMN PPO 日本三菱工程 GX1100 BK LCP美國杜邦ZE16103 WT010 LCP日本東麗L204G35E PVDF 法國阿科瑪 Kynar 461 PA66美國杜邦FE5382 POM 美國泰科納 M450 PPS菲利普R-4-XT PA6德國巴斯夫B29HM01 PC比利時科思創(chuàng)（拜耳） 2097 PP中石化茂名PPH-T03 LCP日本住友化學(xué)SZ6506HF-B PC德國科思創(chuàng)（拜耳） 1897 HDPE沙特SABICF00952 PPO 基礎(chǔ)創(chuàng)新塑料 WCD801A COC德國TOPAS 6013L-17 TPEE美國杜邦DYM350 BK PA6基礎(chǔ)創(chuàng)新塑料PB1006 LM BN 70745 LLDPE中石化茂名DFDA-7042(粉) POM 日本旭化成 3010 ABS臺化AT5500 PC韓國LG GP-2200 BK POM 德國赫斯特 C9021 LS PP日本PBC6D POM 美國泰科納 TX90 PA612 基礎(chǔ)創(chuàng)新塑料 SF-1004-NC PPO 日本旭化成 220Z PBT杭州新光3803 HDPE沙特�？松�美孚HMA-025 PC日本三菱工程 GS3010SR-9001 PMMA 韓國阿科瑪 V040 PC日本出光 LC1200PURE PP北歐化工HH450FB PP上海樂天化學(xué)G-153 PC美國陶氏 303-10 PA66 12TA】PA66 12TA PA66 12TA】PA66 12TA It is divided into three kinds: high pressure method, low pressure method and medium pressure method. High pressure method is used to produce LDPE. This method has been developed very early. Polyethylene produced by this method accounts for about 2/3 of the total output of polyethylene. However, with the development of production technology and catalyst, its growth rate has lagged behind the low pressure method. The low pressure method includes slurry method, solution method and gas phase method for its application. Slurry method is mainly used to produce HDPE, while solution method and gas phase method can not only produce HDPE