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詳細(xì)內(nèi)容:PBT N1000╠PBT N1000 TPEE荷蘭DSM EB460 LCP日本寶理A470 PETG 韓國(guó)SK S2008 PC/ABS 嘉興帝人 TN-7500C BK LCP日本東麗L304X35Z BH PA6德國(guó)巴斯夫B3GK24 BK電木粉 臺(tái)灣長(zhǎng)春 T375HF PP韓國(guó)樂(lè)天化學(xué)JM-375 PA66美國(guó)杜邦54G35HSL LCP日本新石油化學(xué)MG350BPRL/PRL EVA法國(guó)阿科瑪28-420 PA6日本東麗CM1011G-30 SIS美國(guó)科騰D1162BT PA6德國(guó)巴斯夫B27E PBT惠州南亞1410G3 GNC6 LCP日本東麗L204T40 PA66瑞士EMS TSG-30 PA66臺(tái)灣新光N602G6S PMMA 日本住友化學(xué) MM PBT基礎(chǔ)創(chuàng)新塑料430 BK PPS日本寶理1130A1 SEBS中石化巴陵YH-602T PETG 韓國(guó)SK KN200 PC日本三菱工程 S-3000VR TPEE荷蘭DSM PL380 LDPE新加坡聚烯烴F410-3 TPV 美國(guó)?松梨 211-87 LDPE韓國(guó)LGFB9500 TPU臺(tái)灣拜耳優(yōu)得V-64D PBT韓國(guó)LGGP-1006FD PC日本三菱工程 S-3000UR PA6T 日本三井化學(xué) C630 BK PVC河北金牛SE-700 PA6T 美國(guó)杜邦 FR52G30NHF PC基礎(chǔ)創(chuàng)新塑料(南沙) ML1655R-701 PBT N1000╠PBT N1000 PBT N1000╠PBT N1000 HIPS Impact resistant polystyrene (HIPS) is an impact resistant polystyrene product produced by adding polybutadiene rubber particles in polystyrene. introduce 475 is the HIPS machining PBT N1000╠PBT N1000 PA66美國(guó)杜邦HTNFR52G15L NC010 POM 韓國(guó)可隆 K300 POM 南通寶泰菱 F20-02 PA6日本三菱工程1015G15 PMMA 日本旭化成 560F TPV 土耳其英菲力 V0-574-80A PA66臺(tái)灣南亞6210G9 PBT基礎(chǔ)創(chuàng)新塑料(上海)508-1001 POM 泰國(guó)三菱工程 UR20H PA6基礎(chǔ)創(chuàng)新塑料EXKD0038 PA66意大利波利.布蘭德A SG PA612 德國(guó)贏創(chuàng)德固賽 EX9350 BK PA12 瑞士EMS TR90 BK PC日本三菱工程 GBV-2020R PC伊朗國(guó)家石化 PGPC1215 HIPS臺(tái)灣國(guó)喬PS-350K POM 基礎(chǔ)創(chuàng)新塑料 KL-004 POM 日本三菱工程 C10 MBS美國(guó)羅門哈斯EXL2690 PC日本三菱工程 LGV-2220KR PPO 基礎(chǔ)創(chuàng)新塑料 PX1005X PP臺(tái)灣李長(zhǎng)榮6524 PC上海三菱瓦斯 S-3000R EAA美國(guó)杜邦3440 PA66法國(guó)羅地亞B50H1 POE泰國(guó)陶氏8480 PPS日本出光C-140SC LLDPE沙特FD 21HN PPS菲利普BR-42C POM 日本寶理 FX-11J EVA西班牙雷普索爾PA-461 PA66德國(guó)巴斯夫H2 G35 V0KVB1 TPU臺(tái)灣1085APC日本三菱工程 GS-2020MR2 PA66瑞士EMS AG-15/2 PBT N1000╠PBT N1000 PBT N1000╠PBT N1000 The impact resistance of PS can be processed by many traditional molding methods, such as injection molding, structural foam molding, sheet and film extrusion, hot forming and blow molding. HIPS resin absorbs water slowly, so there is no need for drying in general. Sometimes excessive moisture on the surface of the material will be absorbed, which affects the appearance quality of the final product. Under the temperature of 160 F dry 23h can remove excess moisture. The extrusion of thin films, sheets and profiles is the most useful processing method for HIPS. Anti impact polystyrene has a wide range of processing, so it becomes one of the most easily thermoforming resins. Generally, the melting temperature of the resin is 400 - 500 F, and the melt index range of the resin is 1.5 - 4 g/10min. Rotating, series and shuttle type pressure and vacuum thermoforming equipment are often used. HIPS has excellent thermal stability and shear stability. It can be used for a lot of recycled materials without reducing the performance of products, and the amount of recycled material in hot forming can be as high as 60%. PBT N1000╠PBT N1000 PA6德國(guó)巴斯夫B3U PP韓國(guó)樂(lè)天化學(xué)J-550S PP韓國(guó)LG GP-1000FC PBT江蘇三房巷4300G30 PPS日本寶理1140T11 TPEE日本東洋紡織P-40B ABS韓國(guó)LGTR-556 LDPE新加坡聚烯烴F410-7 ABS韓國(guó)三星HF-0660IW TPU臺(tái)灣NX-60A PP韓國(guó)韓華道達(dá)爾HR100 PEI 基礎(chǔ)創(chuàng)新塑料 EC1006-BK EVA新加坡聚烯烴H2020 PA12 瑞士EMS L25 NAT TPE美國(guó)吉力士G7960-9001-02PEEK 美國(guó)殼牌 D26HM100-NC POM 日本旭化成 AK751 TPU德國(guó)科思創(chuàng)(拜耳)UE-85AU10 PC嘉興帝人 L-1225LM PC日本出光 G-2540 TPU德國(guó)科思創(chuàng)(拜耳)255(粉) PC日本三菱工程 LDS 3760 PP中石油蘭州T30S PEI 基礎(chǔ)創(chuàng)新塑料 EC006PXQ PBT日本杜邦SK662FR BK507 PP北歐化工KB4436 PPO 基礎(chǔ)創(chuàng)新塑料 GTX6009 POE美國(guó)陶氏8540 PPS日本東麗A680M PEEK 英國(guó)威格斯 150GL30 POM 美國(guó)杜邦 927UV PA6/66德國(guó)巴斯夫C3U TPU臺(tái)灣拜耳優(yōu)得V-98A PC嘉興帝人 L-1225LPVC臺(tái)灣臺(tái)塑C-1250M PBT N1000╠PBT N1000 PBT N1000╠PBT N1000 Injection molding is the most used processing method next to the extrusion. The injection molding of the resin is usually carried out on a reciprocating screw injection molding machine with a length to diameter ratio of 16:1 to 24:1 and a compression ratio of 2.5/1 - 3.0/1. The processing temperature is 350 - 500 degree F, but for the flame retardant HIPS, the processing temperature must be less than 470 F to prevent the additive from producing degradation reaction. The melt index of the resin processed by injection molding is generally 5 to 15 g/min. The forming method of structural foam plastics is a common process, using chemical and physical foaming agents. Although a variety of HIPS resin are compatible with each other, but before the operation to clean processing equipment, to ensure good product quality, the impact of acrylonitrile with a PS Th ene styrene copolymer (ABS), polyvinyl chloride (PVC), polypropylene (PP), polyethylene (PE), acrylic resin and most other plastics are not compatible, incompatible plastic mixture separation will produce delamination phenomenon in processing equipment, caused great decline of physical properties. application PBT N1000╠PBT N1000 PA6無(wú)錫朗盛BC30S LCP美國(guó)蘇威G-930-BK PC日本三菱工程 HL-3503 PVC韓國(guó)韓華EM-2070 POM 基礎(chǔ)創(chuàng)新塑料 PDX-K-05014 PA66日本三菱工程3010GN15 PA12 法國(guó)阿科瑪 2002 D NAT PBT日本三菱工程5010G-30 PA6T 日本三井化學(xué) E430NK-T5 BK LDPE荷蘭陶氏PG 7008 PA66德國(guó)DOMO66FLH POM 德國(guó)巴斯夫 N2640Z6 PA66惠州南亞6210G9 ABS中石油蘭州3301 POM 德國(guó)泰科納 C13031PC韓國(guó)三星 EH-1051 TPU德國(guó)巴斯夫1154D50 LCP日本杜邦1130 BK010 TPU美國(guó)路博潤(rùn)2363-90AE PC嘉興帝人 LN-1250G BK EVA美國(guó)杜邦3176 HIPS美國(guó)陶氏MC79 PA11 法國(guó)阿科瑪 BESN P40 BLK TL PBT臺(tái)灣長(zhǎng)春4830 NCF LCP日本寶理E473i BK210P ABS韓國(guó)LGMP-211 POM 深圳杜邦 DE-20279A ABS韓國(guó)LGTR-530F PP臺(tái)灣臺(tái)化K9010 TPV 美國(guó)埃克森美孚 8221-85M300 PP臺(tái)灣臺(tái)化K8009 PA612瑞士EMS TV-3H POM 韓國(guó)工程塑料 ET-20A PC德國(guó)科思創(chuàng)(拜耳) TP2021 PP美國(guó)英力士L12Z-01 PBT N1000╠PBT N1000 PBT N1000╠PBT N1000 Impact resistance PS is easily machinability, good performance and low price, so it is used to manufacture products and industrial products of many uses. The main applications are packaging and disposable supplies, instruments, household appliances, toys and entertainment supplies, and construction industries. The largest use of HIPS is to be used as a packaging and disposable material, especially for food packaging and eating tableware. The main applications include the daily packaging container. A cup, a variety of covers, plates, bowls, etc. are used and distributed for the vending machine. Disposable products such as disc, bottle cap, safety razor, pen and so on are also a part of the use of HIPS. PVC carcinogen, which will undoubtedly affect the development of PVC to some extent. However, the residual VCM has been successfully reduced by vehicle and other ways, so that the content of VCM in PVC resin will be less than 10ppm, which will meet the requirement of hygienic grade resin and expand the application scope of PVC. Even the content of VCM in the resin is less than 5ppm, and the residual VCM is very few after processing. It is basically harmless to the human body and can be used as food and medicine packaging and children's toys. Main classification PBT N1000╠PBT N1000 PBT臺(tái)灣長(zhǎng)春5630-104A PPO 基礎(chǔ)創(chuàng)新塑料 WCP781-BK1066 PPS日本東麗A305M D1 PC基礎(chǔ)創(chuàng)新塑料 HF1130-112 TPE德國(guó)膠寶TC5GPZ-S340 PMMA 臺(tái)灣奇美 CM-211 PA46荷蘭DSM TE250F6 GY TPU臺(tái)灣拜耳優(yōu)得UT-85A10 PA66瑞士EMS TSV0 POE美國(guó)埃克森美孚0201PC基礎(chǔ)創(chuàng)新塑料(南沙) 223S PBT日本杜邦CE2720 BK PA6T 日本三井化學(xué) A330K ABS韓國(guó)三星HF-0660I AS(SAN)寧波臺(tái)化NF2200AE PC基礎(chǔ)創(chuàng)新塑料 DF-FR BK PA6美國(guó)舒爾曼6 NV 12FR PP北歐化工HD915CF PEI 基礎(chǔ)創(chuàng)新塑料 2110R-7301 TPV 美國(guó)?松梨 8221-65 PC日本帝人 GN-3410 PP韓國(guó)SK HX3700 PP中石化上海H2800 EVA美國(guó)杜邦1810 POM 日本三菱工程 FB2025 BK TPU美國(guó)RON R395U PA6日本宇部1015GC3 ABS/PMMA 韓國(guó)三星 BF-0370 PP中石化廣州GJ640G PA66德國(guó)巴斯夫A3ZG6 K(Q)膠德國(guó)巴斯夫684D PVC德國(guó)E72CF PC韓國(guó)LG SR-3108FC WL22P PA6韓國(guó)巴斯夫8202 PP泰國(guó)石化230 PBT N1000╠PBT N1000 PBT N1000╠PBT N1000 According to the different application range, PVC can be divided into general PVC resin, high degree of polymerization PVC resin and crosslinked PVC resin. The general PVC resin by polymerization of vinyl chloride monomer is formed under the action of initiator; high degree of polymerization of PVC resin is resin in the polymerization of vinyl chloride monomer added to the system, the chain growth polymerization crosslinking agent; PVC resin is added to the resin crosslinking agent containing dienes and polyenes in vinyl chloride monomer polymerization polymerization system. According to the method to distinguish the vinyl chloride monomer, can be divided into electric stone, and imported ethylene (EDC, VCM) monomer method (on the habits of the ethylene monomer and import system called ethylene method). According to polymerization method, PVC can be divided into four main categories: suspension polyvinyl chloride, emulsion polymerization, polyvinyl chloride, bulk polymerization, polyvinyl chloride and solution polyvinyl chloride. Suspension polyvinyl chloride (PVC) is one of the most productive varieties, accounting for about 80% of the total output of PVC. Polyvinyl chloride suspension method is divided into six models according to absolute viscosity: XS-1, XS-2... XS-6; XJ-1, XJ-2... XJ-6. The meaning of each letter in the model: X- suspension; S- loose type; J- compact. method PBT N1000╠PBT N1000 EPDM 韓國(guó)SK S512F LDPE沙特巴塞爾LP 2427K MBS日本鐘淵M521 PA66漳州長(zhǎng)春20G3 TPU臺(tái)灣拜耳優(yōu)得UT-64DU10 PC基礎(chǔ)創(chuàng)新塑料 FL900 PC/ABS 臺(tái)灣臺(tái)化 AC2100 LDPE新加坡埃克森美孚LD 165BW1 PP新加坡聚烯烴FL7015E2 PP東莞韓華道達(dá)爾TB54 TPU韓國(guó)SK S364DH OBC美國(guó)陶氏9000 TPU德國(guó)巴斯夫1085A53 PBT日本三菱工程5010R5 TPEE美國(guó)杜邦30D POM 日本三菱工程 UR20H PP臺(tái)灣福聚ST868K ABS韓國(guó)LGTR-558AI PC日本出光 LC1300 PP韓國(guó)大林RP373R PPS臺(tái)灣寶理E1140 LLDPE沙特FC 21HN PA12 德國(guó)贏創(chuàng)德固賽 L1940 PMMA 南通三菱麗陽(yáng) VH5000 PC上海三養(yǎng) 3025N1BK EVA韓國(guó)韓華1316 AS(SAN)臺(tái)灣奇美PN-117L200 POE美國(guó)陶氏8400 PC基礎(chǔ)創(chuàng)新塑料 HPS1-1125 PA66美國(guó)杜邦408HSL PC基礎(chǔ)創(chuàng)新塑料 DL-4520 BK PP茂名實(shí)華003 PP寧波甬興E140 PA6日本三菱工程1015G20 PA12 德國(guó)贏創(chuàng)德固賽 LX9008 PBT N1000╠PBT N1000 PBT N1000╠PBT N1000 polyvinyl chloride PVC can be made by substitution reaction of ethylene, chlorine and catalyst. Because of its fire prevention heat effect of PVC is widely used in all walks of life every kind of products: wire skin, skin fiber, shoes, handbags, bags, accessories, signs and billboards, building decoration supplies, furniture, ornaments, rollers, pipes, toys (such as the famous Italy "Rody" jumping horse), curtain, door, auxiliary medical supplies, gloves, some food preservation paper, some fashion etc.. Polymerization method PVC was prepared by free radical addition polymerization. The polymerization methods were mainly divided into suspension polymerization, emulsion polymerization and bulk polymerization, mainly by suspension polymerization, which accounted for about 80% of the total output of PVC. The pure water, liquefied VCM monomer and dispersant were added to the reactor, then initiator and other auxiliaries were added. After heating to a certain temperature, the VCM monomer was polymerized by free radical to form PVC particles. Continuous stirring makes the particle size uniform and makes the generated particles suspended in the water. In addition, the PVC paste resin was produced by micro suspension, and the properties and paste properties of the products were all good. PBT N1000╠PBT N1000 PPS日本出光NT-7790 ABS日本UMGTM-35 PMMA 韓國(guó)阿科瑪 V825 POM 美國(guó)赫斯特 C13031XF PA6德國(guó)朗盛BKV30 FN 000000 LCP日本杜邦5145L-WT010 PBT臺(tái)灣長(zhǎng)春3020-201 PP泰國(guó)HMCRC213M POM 日本旭化成 LT-805 PC日本三菱工程 CGF2007R PBT臺(tái)灣新光4880 PC臺(tái)灣臺(tái)化出光 IR2200 CBPPS日本寶理1140A42 HF200 PP中石化上海F800EPC基礎(chǔ)創(chuàng)新塑料 HF1130 PC美國(guó)陶氏 301 BK PA66美國(guó)泰科納GF60-01 PA6德國(guó)巴斯夫B3WEG6 PC日本帝人 ML-3206ZT EPDM 美國(guó)陶氏 4520 POM 美國(guó)泰科納 S9243 PBT惠州南亞1403G6 GBK3 POM 日本杜邦 500P PFA 日本大金 ACX-31 PC荷蘭DSM J/50/10/TF/15 BK PA12 日本宇部 3030JI12L PA66基礎(chǔ)創(chuàng)新塑料QL4540 PC基礎(chǔ)創(chuàng)新塑料 EXRL0925 PC基礎(chǔ)創(chuàng)新塑料 DE0026E PC/ABS 基礎(chǔ)創(chuàng)新塑料 FXE1414L PP基礎(chǔ)創(chuàng)新塑料M3000 PA12 德國(guó)贏創(chuàng)德固賽 CX9703 LCP日本杜邦5145L-WT010PC基礎(chǔ)創(chuàng)新塑料 LUX9616 PA66惠州南亞6410G5 ABK3 PBT N1000╠PBT N1000 PBT N1000╠PBT N1000 The monomer droplets are dispersed in the aqueous phase suspension polymerization method, using oil soluble initiator were dissolved in monomer, polymerization reaction in the droplet, the polymerization heat absorbed by the water in time, in order to ensure that these droplets in water were bead dispersed, need to join the suspension the stabilizer, such as gelatin and polyvinyl alcohol, methyl cellulose, hydroxyethyl cellulose, etc.. Most of the initiators are organic peroxide and azo compounds, such as peroxide two, two isopropyl carbonate, peroxide two, bicarbonate, peroxide two, two ethylhexyl ester, azo two isoheptane, azo two isobutadiene and so on. The polymerization is carried out in a polymerizer with a agitator. After polymerization, the monomer material flows into the recovery tank or stripper recycle monomer. Then into the mixing kettle, water washing then centrifuge dehydration, drying and resin finished products. The vinyl chloride monomer should be removed from the resin as much as possible. As the PVC for food packaging, the content of free monomer should be controlled below 1ppm. During polymerization, the temperature and pressure of the polymerization process must be controlled to ensure that the specified molecular weight and molecular weight distribution range are obtained and the detonation is prevented. The particle size and particle size distribution of the resin is controlled by the stirring speed and the selection and dosage of the suspension stabilizer. The quality of resin is characterized by particle size and particle size distribution, molecular weight and molecular weight distribution, apparent density, porosity, fisheye, thermostability, color, impurity content and free mobility of powder. Polymerization reaction
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