詳細內(nèi)容：PA12 3030LUX¤PA12 3030LUX PP北歐化工HC115FB PP寧波臺塑1252F PBT漳州長春3015-104/201 PA6德國朗盛TP754-321 PPS日本油墨CRZ1400 ABS臺灣國喬D-650 PC日本三菱工程 GS2020MKR TPE德國膠寶TF6FMA-S340 AES 日本TECHNO W220 PC日本帝人 L-1225L BK PA6T 美國杜邦 HTN52G35HSL PP韓國樂天化學JC160 PVDF 法國蘇威 6020 POM 美國杜邦 16-2 PA6日本三菱工程1010C ABS韓國錦湖HFA705 PC新加坡帝人 L-1250Z100 PA46日本DSM TQ261F5 BK PC美國陶氏 4731 PEI 基礎創(chuàng)新塑料 EF-1004 BK PBT德國科思創(chuàng)（拜耳）B3235 PA66基礎創(chuàng)新塑料RFL-4034 PA66美國杜邦FR52G30NH NC LCP日本住友化學E6810GHF ABS荷蘭盛禧奧（斯泰�。�3325MT PA46日本DSM N2030B PA612 基礎創(chuàng)新塑料 IF006S PC基礎創(chuàng)新塑料(南沙) EXL1414 LDPE沙特SABICLD 165BW1 PA46荷蘭DSM TC153 PA66德國朗盛A30SFN31 PPS日本油墨CZE-1400 PA12 法國阿科瑪 MS1100 PA66法國羅地亞A218V40 BK EVA美國杜邦2815 PA12 3030LUX¤PA12 3030LUX PA12 3030LUX¤PA12 3030LUX LLDPE The production of LLDPE begins with the transition metal catalyst, especially the type of Ziegler (Ziegler) or PHILPS Phillips. A new process based on the catalyst for the cyclic olefin metal derivatives is another option for LLDPE production. The actual polymerization can be carried out in the solution and gas phase reactor. Both LDPE and LLDPE have excellent rheological or melt fluidity. LLDPE has smaller shear sensitivity because it has a narrow molecular weight distribution and a short branched chain. During the shear process (for example, extrusion), LLDPE maintains a greater viscosity, and thus is difficult to be processed than the same melting index of LDPE. In extrusion, the lower shear stress of LLDPE makes the stress relaxation of polymer chains faster, and the sensitivity of physical property to the change of blow up ratio is reduced. In the melt extension, LLDPE usually has lower viscosity at various strain rates. That is to say, it will not strain hardening as the LDPE is stretched. The increase in the deformation rate of polyethylene (.LDPE) shows an astonishing increase in viscosity, which is caused by molecular chain entanglement. This phenomenon is not observed in LLDPE, because the lack of long branched chains in LLDPE makes the polymer not entangled. This performance is very important for the application of thin films, because the LLDPE thin films are easy to make thin films under high strength and toughness. Classification /LLDPE PA12 3030LUX¤PA12 3030LUX LCP日本杜邦5145L-WT010 PBT臺灣長春3020-201 PP泰國HMCRC213M POM 日本旭化成 LT-805 PC日本三菱工程 CGF2007R TPU德國科思創(chuàng)（拜耳）B90A SEBS臺灣臺橡6154 PP沙特巴塞爾M4 U02 PBT日本東麗1200M PETG 美國伊士曼 CM155 PP臺灣南亞3210G6F LLDPE美國陶氏2607G TPU美國RON R390UPC/ABS 上�？扑紕�(chuàng)（拜耳） FR3008HR PBT美國杜邦S660FR NC010 PA66德國巴斯夫A3X2G5 BK TPV 美國�？松�美孚 123-52W242 PC臺灣臺化 AC2821-AH PBT江蘇長春1100-211 PA66深圳杜邦70G33L BK031 POM 日本旭化成 4060 PA66河南神馬尼龍EPR2702 LCP美國泰科納LKX-1324 PA6德國科思創(chuàng)（拜耳）B3G6 HIPS臺灣臺達666 PBT瑞士EMSB24H POM 韓國工程塑料 FU2025 PBT臺灣新光B0620FC BK PBT日本東麗1101H TPEE美國杜邦HTR8206 TPU臺灣S-172D PCT 美國杜邦 CG943 LDPE卡塔爾石化LA0710 CAB美國伊士曼551-0.01PETG 韓國SK KN100 PA12 3030LUX¤PA12 3030LUX PA12 3030LUX¤PA12 3030LUX LLDPE Atlas According to the type of copolymerized monomers, LLDPE is mainly divided into 3 kinds of copolymers: C4 (butene -1), C6 (hexene -1) and C8 (octene -1). Among them, butylene copolymer is the largest LLDPE resin in the world, while hexene copolymer is the fastest growing LLDPE variety at present. In the LLDPE resin, the typical dosage of the copolymerized monomer is 5% to 10%, with an average amount of about 7%. The metallocene based LLDPE plastic body (mLLDPE) has more than 3 times the average content of the average copolymerized monomer of the traditional LLDPE. Figure 1 shows that the world is 10 years since their 3 monomers yield of LLDPE. At the end of 1984, the co carbon company introduced the production of hexene copolymerized LLDPE, followed by Exxon, Mobil and other companies. Dow Chemical (Dow Chemical Company) almost used octylene as comonomer in its low pressure solution process, and NOVA Canada (Nova chemical) also used octylene in most of the pressure solution process. The copolymerization of octyl LLDPE resin has a little good strength, tearing resistance and processing property, but the properties of hexene copolymerization and octyl copolymers have little difference. Hexene LLDPE resin manufacturers including ExxonMobil Chemical (Exxon Mobil chemical company), Eastman Chemical (Eastman Chem Co), Equistar (star company) and Chevron Phillips (Chevron Phillips chemical company) etc.. In addition, Dow Chemical (Dow Chemical Company), Basell (Basel), Innovene (Samsung, Total, innoven) (Samsung Total (micro-blog), etc.) also produce 1-hexene LLDPE. Compared with the commonly used butene copolymers, the LLDPE produced by hexene and octene as copolymerized monomers has better performance. The largest use of LLDPE resin in film production, with a long chain alpha olefin (such as cyclohexene, 1-octene) as comonomer production of LLDPE resin and film products in the tensile strength, impact strength, tearing strength, penetration resistance, environmental stress cracking resistance and many other aspects are better than by butene as comonomer to produce LLDPE resin. Since 1990s, PE manufacturers and users in foreign countries tend to replace butylene with hexene and octene. It is reported that using octene as comonomer, the performance of resin is not necessarily better than that of hexene copolymerization, and the price is more expensive. Therefore, the trend of using LLDPE abroad to replace butene is more obvious. PA12 3030LUX¤PA12 3030LUX EVA美國杜邦460 LCP美國杜邦7145 WT010 PP韓國韓華道達爾BJ550 PBT美國杜邦S620F20 PA46荷蘭DSM TC155 ABS遼寧華錦化工8391 LDPE日本旭化成F1920P PPO 基礎創(chuàng)新塑料 PX1700X-80403 EPDM 韓國SK S552 TPU德國巴斯夫ED-95A50U POM 日本旭化成 AK510 CA美國伊士曼132E 5243231 HDPE泰國PTT化學8100M PA66意大利LATI66 H2 G/25 V0 CT1 LDPE新加坡聚烯烴F108-5 PA46荷蘭DSM TW241F8 BK TPV 美國�？松�美孚 8291-85TL PC日本帝人 G-3510M SEBS日本可樂麗4033 PC日本帝人 LV-2250Z PC日本三菱工程 CF-2030 POM 日本寶理 KT-20 TPEE美國杜邦45D PA66基礎創(chuàng)新塑料RBL-4316HI PA9T 日本可樂麗 GX1500A BK ABS韓國三星GR-4020 AS(SAN)德國科思創(chuàng)（拜耳）52485 PEI 基礎創(chuàng)新塑料 AUT195 TPU美國RON R195 PFA 日本大金 AP-230 PC基礎創(chuàng)新塑料 ML6411 TPE臺灣和泰HT45 PPS日本東麗A575W20 PA12 瑞士EMS XE3784 BU PC日本三菱工程 GS2010MPH PA12 3030LUX¤PA12 3030LUX PA12 3030LUX¤PA12 3030LUX Because there is no large-scale production of hexene and octene in China, and the import price is more expensive, the LLDPE resin currently used in China is mainly used as butene as comonomer. Some enterprises in China used the LLDPE as the monomer of the comonomer when they introduced the production plant, but they had to give up because of the production of no hexene in China, and only imported a small amount of hexene when driving. Most of the high grade LLDPE imported from China are such products. It is expected that in the future, there will be a greater increase in the demand for LLDPE with 1- hexene as a monomer. Performance /LLDPE Cold tolerance of LLDPE, the relationship between catalytic temperature and melt flow rate of LLDPE brittle temperature than LDPE, HDPE are low, which indicates that the resistance to low temperature. Physical and mechanical properties PA12 3030LUX¤PA12 3030LUX PA66上海羅地亞A216V15 PC/PET 美國伊士曼 DA003-8906K PPO 基礎創(chuàng)新塑料 PX9406X PP臺灣臺塑5350T PA66基礎創(chuàng)新塑料RF-7007HS BK PC上�？扑紕�(chuàng)（拜耳） EM9417 PBT基礎創(chuàng)新塑料310-1001 PPO 日本三菱工程 GX1100 BK PBT深圳東麗1164G-30PC基礎創(chuàng)新塑料(南沙) 500ECR PA66美國首諾21SPC PVC香港利澤F-80A PEI 基礎創(chuàng)新塑料 6202 PPS菲利普R-4-220BL PA6日本東麗CM1001RPVDF 法國阿科瑪 1000HD PC基礎創(chuàng)新塑料 DX07350 TPU上海巴斯夫1198A10PC德國科思創(chuàng)（拜耳） APEC 1895 K(Q)膠德國巴斯夫2G66 PBT韓國杜邦SK602-BK851 PA66美國杜邦EFE6096 PBT日本寶理201NFED3002 PC基礎創(chuàng)新塑料(南沙) ML1848-X13738L TPU德國巴斯夫ES80A11 PP臺灣臺塑4084 PP北歐化工HOE111NP LDPE中石化齊魯2102TN26 PBT日本寶理7307 GY EVA寧波臺塑7470M TPEE臺灣長春1140MH1 PA46荷蘭DSM TW242FM10 PPS日本東麗A670 PEEK 基礎創(chuàng)新塑料 LL004C LCP日本新石油化學MG350-A540 PA12 3030LUX¤PA12 3030LUX PA12 3030LUX¤PA12 3030LUX MDPE molecular structure In the main chain of MDPE molecule, there are 20 methyl branched chains or 13 ethyl branched chains on the average of every 1000 carbon atoms, and their performance depends on the number and length of branched chain. Copolymerization can increase the link chain between small crystals of its crystal Performance characteristics and parameters MDPE is characterized by long term retention of resistance to environmental stress and strength. The relative density of MDPE is 0.926-0.953, the crystallinity of 70%-80%, the average molecular weight is 200 thousand, the tensile strength is 8-24 MPa, elongation at break of 50%-60%, the melting temperature of 126-135 DEG C, the melt flow rate of 0.1-35 g /10 minutes, the heat deformation temperature of 49-74 DEG C (0.46 MPa). Processing technology PA12 3030LUX¤PA12 3030LUX PC上海三菱瓦斯 GSH2010LR TPU臺灣拜耳優(yōu)得V-90A PBT日本三菱工程7025GRU20 TPV 荷蘭DSM X4339DN-V0 POE西班牙陶氏3200 TPEE美國杜邦SC952 PA66日本EMS AG-30/10 PP韓國韓華道達爾HY200 PETG 美國伊士曼 AN001 PBT日本三菱工程5010GN1-30LAM-BK POM 日本杜邦 DE-8903 POM 德國巴斯夫 N2200G5 TPU德國巴斯夫1185A10U PETG 美國伊士曼 GN120 ABS中石油吉化0215H PP中石化茂名BMT25S TPU德國科思創(chuàng)（拜耳）UH-71DU20 TPV 美國埃克森美孚 271-80 PP泰國石化300S PC日本帝人 G-3410 PA12 瑞士EMS FE4495 PA6德國巴斯夫B40 LN01 PMMA 日本三菱麗陽 IRH-30 PETG 美國伊士曼 GN071 PBT美國NyleneRG301 BK PBT日本三菱工程5308G45 PC/ABS 德國科思創(chuàng)（拜耳） FR3006 TPU上海亨斯邁65AB PP泰國石化1126NK PBT臺灣新光F202G15 TPV 荷蘭DSM X4339DN-V0 PA66美國杜邦HTN53G50HSLHF PA66上海巴斯夫A3EG7 OBC美國陶氏9000 TPE美國吉力士CL2042X PA12 3030LUX¤PA12 3030LUX PA12 3030LUX¤PA12 3030LUX It is divided into three kinds: high pressure method, low pressure method and medium pressure method. High pressure method is used to produce LDPE. This method has been developed very early. Polyethylene produced by this method accounts for about 2/3 of the total output of polyethylene. However, with the development of production technology and catalyst, its growth rate has lagged behind the low pressure method. The low pressure method includes slurry method, solution method and gas phase method for its application. Slurry method is mainly used to produce HDPE, while solution method and gas phase method can not only produce HDPE